WebSix different nanoarchitectures were constructed by a series of synthetic bio-inspired chiral porphyrin dimers through molecular self-assembly behaviour. A plausible mechanism of chiral expression from the molecular to the macroscopic levels was investigated through an analysis of the optical spectroscopy and theoretical calculations. WebMolecular assemblies of two achiral porphyrins with different substituents, 5-(4-methoxycarbonylphenyl)-10,15,20-triphenyl-21H,23H-porphine (TPPCOOMe) and 5-(4-carboxyphenyl)-10,15,20-triphenyl-21H,23H-porphine (TPPCOOH), have been fabricated by the Langmuir–Blodgett (LB) technique. It is disclosed that although only slight differences …
IJMS Special Issue : Porphyrin and Biomolecules: A Long-Lasting ...
WebJan 1, 2013 · Liu and coworkers reported, for example, on the formation of chiral porphyrin assemblies in chiral gel, formed by DMSO and a low molecular weight chiral gelators, with transfer of chirality to the whole condensed phase . The organic gelators are the N,N′-bis(octadecyl)-l-Boc-glutamic diamide and its d-isomer (60). These ... WebApr 1, 2024 · The formation of chiral porphyrin assemblies can be from porphyrin molecules substituted with chiral groups; achiral porphyrins induced by chiral additives … optimal speed courier
Anion-Controlled Assembly of Porphyrin−Bicyclic Guanidine Conjugates ...
WebNov 23, 2024 · Inspired by the hierarchical chiral assembly of porphyrin-proteins in photosynthetic systems, the hierarchical self-assembly of porphyrin-amino acids/peptides provides a novel strategy for constructing functional materials. How to artificially simulate the assembly of porphyrins, proteins, and other cofactors in the photosynthesis system to ... WebJan 1, 2024 · The self-assembly of achiral 11 and chiral 12 and 13 porphyrins have been studied in aqueous media with the addition of chiral amines co-solutes. The influence of … WebAug 7, 2024 · The L (D)-CDots+H 2 TPPS solution was prepared by mixing the chiral carbon dots (150 μg/mL) and H 2 TPPS solution (100 μM) at pH = 6.5. After incubation for 30 min, the pH dropped to 2.5 and porphyrin … portland or weather radar map